Predicting the regioselectivity of arynes: a simple model based on orbital electronegativity-Reference-Cited by-同舟云学术

Predicting the regioselectivity of arynes: a simple model based on orbital electronegativity

Published:2019 Issue:3 Volume:43 Page:1130-1133
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Mirzaei Saber¹²³⁴^ORCID,Khosravi Hormoz⁵⁶⁷⁸^ORCID

Affiliation:

1. Department of Chemistry

2. Marquette University

3. Milwaukee

4. USA

5. Faculty of Chemistry

6. K. N. Toosi University of Technology

7. Tehran

8. Iran

Abstract

A simple model based on orbital electronegativity to predict the regioselectivity of arynes is reported; the nucleophiles attack the terminus possessing lower OE.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/NJ/C8NJ04027C

Reference45 articles.

1. R. Sanz and A.Suárez , The Chemistry of Arynes, in Arene Chemistry: Reaction Mechanisms and Methods for Aromatic Compounds , ed. J. Mortier , John Wiley & Sons, Inc , Hoboken , 2015 , pp. 301–333

2. A Closer Look at Aryne Chemistry: Details that Remain Mysterious

3. Regioselective Reactions of Highly Substituted Arynes

4. Facile N-Arylation of Amines and Sulfonamides and O-Arylation of Phenols and Arenecarboxylic Acids

5. Strain-Induced Regioselectivities in Reactions of Benzyne Possessing a Fused Four-Membered Ring

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