Shape-adaptive single-molecule magnetism and hysteresis up to 14 K in oxide clusterfullerenes Dy2O@C72 and Dy2O@C74 with fused pentagon pairs and flexible Dy–(μ2-O)–Dy angle-Reference-Cited by-同舟云学术

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Shape-adaptive single-molecule magnetism and hysteresis up to 14 K in oxide clusterfullerenes Dy2O@C72 and Dy2O@C74 with fused pentagon pairs and flexible Dy–(μ2-O)–Dy angle

Published:2020 Issue:18 Volume:11 Page:4766-4772
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Velkos Georgios¹²³^ORCID,Yang Wei⁴⁵⁶⁷⁸,Yao Yang-Rong⁹¹⁰¹¹¹²¹³,Sudarkova Svetlana M.¹²³¹⁴¹⁵,Liu XinYe⁴⁵⁶⁷⁸,Büchner Bernd¹²³,Avdoshenko Stanislav M.¹²³^ORCID,Chen Ning⁴⁵⁶⁷⁸^ORCID,Popov Alexey A.¹²³^ORCID

Affiliation:

1. Leibniz Institute for Solid State and Materials Research Helmholtzstraße 20

2. 01069 Dresden

3. Germany

4. College of Chemistry

5. Chemical Engineering and Materials Science

6. Soochow University

7. Suzhou

8. P.R. China

9. Department of Chemistry

10. University of Texas at El Paso

11. 500 W University Avenue

12. El Paso

13. USA

14. Chemistry Department

15. Moscow State University

Abstract

Clusterfullerenes Dy₂O@C₇₂ and Dy₂O@C₇₄ demonstrate a fine balance of exchange and dipolar interactions and slow relaxation of magnetization.

Funder

H2020 European Research Council

H2020 Marie Skłodowska-Curie Actions

Deutsche Forschungsgemeinschaft

National Natural Science Foundation of China

Natural Science Foundation of Jiangsu Province

Priority Academic Program Development of Jiangsu Higher Education Institutions

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC00624F

Reference66 articles.

1. When metal clusters meet carbon cages: endohedral clusterfullerenes

2. A. A. Popov , Endohedral Fullerenes: Electron Transfer and Spin , Springer International Publishing , Cham , 2017

3. Endohedral Fullerenes

4. Endohedral Metallofullerenes: New Structures and Unseen Phenomena

5. Mononuclear Clusterfullerene Single-Molecule Magnet Containing Strained Fused-Pentagons Stabilized by a Nearly Linear Metal Cyanide Cluster

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