Highly syndioselective coordination (co)polymerization of vinyl heteroaromatic monomers using rare-earth-metal complexes
Author:
Affiliation:
1. State Key Laboratory of Polymer Physics and Chemistry
2. Changchun Institute of Applied Chemistry
3. Chinese Academy of Sciences
4. Changchun 130022
5. China
6. University of Science and Technology of China
7. Hefei 230026
Abstract
This paper demonstrates the coordination polymerization of vinylbenzothiophene and its copolymerization with styrene with high activity and perfect syndioselectivity to give high molecular weight products by using rare-earth-metal precursors.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering
Link
http://pubs.rsc.org/en/content/articlepdf/2020/PY/D0PY01447H
Reference33 articles.
1. Precise Control of Polyolefin Stereochemistry Using Single-Site Metal Catalysts
2. Copolymerization of Polar Monomers with Olefins Using Transition-Metal Complexes
3. Late-Metal Catalysts for Ethylene Homo- and Copolymerization
4. Coordination Polymerization of Polar Vinyl Monomers by Single-Site Metal Catalysts
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