Highly efficient aqueous phase reduction of nitroarenes catalyzed by phosphine-decorated polymer immobilized ionic liquid stabilized PdNPs

Author:

Doherty S.12345ORCID,Knight J. G.12345ORCID,Backhouse T.12345,Bradford A.12345,Saunders F.12345,Bourne R. A.678910ORCID,Chamberlain T. W.678910ORCID,Stones R.678910,Clayton A.678910ORCID,Lovelock K.211121310ORCID

Affiliation:

1. NUCAT

2. School of Chemistry

3. Bedson Building

4. Newcastle University

5. Newcastle upon Tyne

6. Institute of Process Research and Development

7. School of Chemistry and School of Chemical and Process Engineering

8. University of Leeds

9. LS2 9JT

10. UK

11. Food and Pharmacy

12. University of Reading

13. Reading

Abstract

Phosphino-decorated polymer immobilised ionic liquid-stabilised PdNPs are highly efficient catalysts for the aqueous phase hydrogenation and transfer hydrogenation of aromatic nitro compounds in batch and continuous flow.

Funder

Newcastle University

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Reference111 articles.

1. N. Ono , The Nitro Group in Organic Synthesis , Wiley-VCH , New York , 2001

2. H.-U. Blaser and E.Schmidt , Heterogeneous Catalysis and Fine Chemicals , Elsevier , Amsterdam , 1997 , vol. 4

3. A. S. Travis , in The Chemistry of Anilines , ed. Z. Rappoport , Wiley , 2007 , ch. 13, pp. 715–782

4. Selective Catalytic Hydrogenation of Functionalized Nitroarenes: An Update

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