Distinguishing the mechanism of electrochemical carboxylation in CO<sub>2</sub>eXpanded Electrolytes-Reference-Cited by-同舟云学术

Distinguishing the mechanism of electrochemical carboxylation in CO₂eXpanded Electrolytes

Published:2023 Issue:38 Volume:59 Page:5713-5716
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Stalcup Matthew A.¹²,Nilles Christian K.²³,Subramaniam Bala¹²^ORCID,Blakemore James D.²³^ORCID,Leonard Kevin C.¹²^ORCID

Affiliation:

1. Department of Chemical & Petroleum Engineering, University of Kansas, 4132 Learned Hall 1530 W 15th St, Lawrence, KS, USA

2. Center for Environmentally Beneficial Catalysis, University of Kansas, 1501 Wakarusa Drive LSRL Building A, Suite 110, Lawrence, KS, USA

3. Department of Chemistry, University of Kansas, 1140 Gray-Little Hall, 1567 Irving Hill Road, Lawrence, KS, USA

Abstract

We shed light on the mechanism and rate-determining steps of the electrochemical carboxylation of acetophenone as a function of CO2concentration by using a robust finite element analysis model that incorporates each reaction step.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D2CC06560F

Reference28 articles.

1. What Should We Make with CO2 and How Can We Make It?

2. High Selectivity for Ethylene from Carbon Dioxide Reduction over Copper Nanocube Electrocatalysts

3. Electrosynthesis: Sustainability Is Not Enough

4. Asymmetric Electrochemical Transformations

5. Electrochemical reduction and carboxylation of halobenzophenones