Rh-Catalyzed oxidative homo-coupling cyclization of 2,3-allenols to conjugated furylenones-Reference-Cited by-同舟云学术

Rh-Catalyzed oxidative homo-coupling cyclization of 2,3-allenols to conjugated furylenones

Published:2021 Issue:16 Volume:8 Page:4432-4437
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Wu Xiaoyan¹²³⁴⁵^ORCID,Fan Junjie¹²³⁴⁵^ORCID,Huang Xin¹²³⁴⁵,Ma Shengming¹²³⁴⁵^ORCID

Affiliation:

1. Laboratory of Molecular Recognition and Synthesis

2. Department of Chemistry

3. Zhejiang University

4. Hangzhou 310027

5. People's Republic of China

Abstract

An unexpected rhodium-catalyzed highly regio- and stereo-selective bimolecular nucleophilic oxyrhodation/insertion/1,4-Rh migration/β-H elimination reaction of 2,3-allenols affording (2,5-dihydrofuran-3-yl)but-2(E)-en-1-one derivatives is reported.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/QO/D1QO00599E

Reference41 articles.

1. Cross-Coupling/Cyclization Reactions of Two Different Allenic Moieties

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3. Silver and platinum-catalysed addition of O–H and N–H bonds to allenes

4. Cyclization reactions of bis(allenes) for the synthesis of polycarbo(hetero)cycles

5. Allenes, versatile unsaturated motifs in transition-metal-catalysed [2+2+2] cycloaddition reactions

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