Fine tuning of copper(ii)–chlorophyll interactions in organic media. Metalation versus oxidation of the macrocycle-Reference-Cited by-同舟云学术

Fine tuning of copper(ii)–chlorophyll interactions in organic media. Metalation versus oxidation of the macrocycle

Published:2015 Issue:13 Volume:44 Page:6012-6022
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Orzeł Łukasz¹²³⁴,Szmyd Bartłomiej¹²³⁴,Rutkowska-Żbik Dorota⁵⁶⁷⁴,Fiedor Leszek⁸⁹²¹⁰⁴,van Eldik Rudi¹²³⁴¹¹,Stochel Grażyna¹²³⁴

Affiliation:

1. Faculty of Chemistry

2. Jagiellonian University

3. 30-060 Kraków

4. Poland

5. Jerzy Haber Institute of Catalysis and Surface Chemistry

6. Polish Academy of Sciences

7. 30-239 Kraków

8. Faculty of Biochemistry

9. Biophysics and Biotechnology

10. 30-387 Kraków

11. Inorganic Chemistry

Abstract

The reactivity of Cu(ii) towards chlorophylls can be tuned by slight changes in the composition of the medium, leading to different reaction pathways and products in organic solvents.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT03809F

Reference56 articles.

1. STUDIES ON THE BIOSYNTHESIS OF CHLOROPHYLL: CHEMICAL INCORPORATION OF MAGNESIUM INTO PORPHYRINS

2. Recent overview of the Mg branch of the tetrapyrrole biosynthesis leading to chlorophylls

3. Magnesium-dependent ATPase Activity and Cooperativity of Magnesium Chelatase from Synechocystis sp. PCC6803

4. Mechanism and regulation of Mg-chelatase

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