Electronic and molecular structures of the active-site H-cluster in [FeFe]-hydrogenase determined by site-selective X-ray spectroscopy and quantum chemical calculations-Reference-Cited by-同舟云学术

Electronic and molecular structures of the active-site H-cluster in [FeFe]-hydrogenase determined by site-selective X-ray spectroscopy and quantum chemical calculations

Published:2014 Issue:3 Volume:5 Page:1187-1203
ISSN:2041-6520
Container-title:Chem. Sci.
language:en
Short-container-title:Chem. Sci.

Author:

Lambertz Camilla¹²³⁴,Chernev Petko⁵⁶⁷⁸,Klingan Katharina⁵⁶⁷⁸,Leidel Nils⁵⁶⁷⁸,Sigfridsson Kajsa G. V.⁵⁶⁷⁸,Happe Thomas¹²³⁴,Haumann Michael⁵⁶⁷⁸

Affiliation:

1. Institute for Biochemistry of Plants

2. Department of Photobiotechnology

3. Ruhr-University Bochum

4. 44780 Bochum, Germany

5. Institute for Experimental Physics

6. Freie Universität Berlin

7. FB Physik

8. 14195 Berlin, Germany

Abstract

Site-selective X-ray spectroscopy discriminated the cubane and diiron units in the H-cluster of [FeFe]-hydrogenase revealing its electronic and structural configurations.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/SC/C3SC52703D

Reference121 articles.

1. ‘Renewable’ hydrogen: Prospects and challenges

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3. Review of Developments in Portable Hydrogen Production Using Microreactor Technology

4. The Role of Chemistry in the Energy Challenge

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