Heterometallic boride clusters: formation of octahedral [M2Ru4(CO)16B]–(M = Rh or Ir) and gold(I) phosphine derivatives. Crystal structures of [N(PPh3)2][trans-Ir2Ru4(CO)16B], trans-[Rh2Ru4(CO)16B{µ3-AuP(C6H11)3}] and cis-[Ir2Ru4(CO)16B{µ-AuP(C6H11)3}]
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/1995/DT/DT9950000549
Reference16 articles.
1. Ru3(CO)9BH5 and [Ru3(CO)9BH4]− as precursors to higher nuclearity homo- and heterometallic clusters: molecular structure of a second isomer of HRu6(CO)17B
2. The first trigonal prismatic discrete transition-metal boride cluster: preparation and molecular structure of [PPN][Ru6(H)2(CO)18B][PPN =(Ph3P)2N+]
3. Trigonal-prismatic and octahedral hexaruthenium boride clusters: molecular structures of [N(PPh3)2][Ru6H2(CO)18B], [Ru6(CO)17B{AuP(C6H4Me-2)3}], [Ru6H(CO)16B{Au(PPh3)}2] and [Ru6(CO)16B{Au(PPh3)}3]
4. Syntheses and molecular structures of two boride cluster anions: octahedral [Rh2Ru4(CO)16B]? and double-prismatic [Rh3Ru6(CO)23B2]?
5. Synthesis and structure of the ruthenium carbonyl "boride" cluster HRu6(CO)17B
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