A general method of generating agostic interaction between RuIIand C–H bonds of tert-butyl, methyl, aryl, heterocyclic or alkenyl groups using azine phosphines
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/1995/DT/DT9950003861
Reference25 articles.
1. New bidentate ligands PPh2CH2C(But)NNR2(R = H or Me) and PPh2CH2C(But)NNCHPh and their complexes with Group 6 metal carbonyls
2. Terdentate (P–N–O) complexes formed from Z,E-PPh2CH2C-(But)N–NCH(C6H4OH-2) or Z,E-PPh2CH2C(But)N–NCH-[C6H2(OH-2)(OMe)2-4,6] and nickel, palladium, platinum, rhodium or iridium
3. A general method of promoting oxidative addition of C–H bonds to iridium(I) using azine phosphines
4. Cyclometallation of a pentafluorobenzaldehyde azine phosphine via a CF bond fission by irridium(I): crystal structure of [IrCl2(CO){Ph2CH2C(But) = NN = CH(C6F4}]
5. General strategy for inducing C–H bond fission (cycloiridation) in some aryl, heterocyclic, alkenyl or alkyl groups in azines derived from aldehydes or methyl ketones
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1. Agostic bonds in cyclometalation;Journal of Organometallic Chemistry;2011-03
2. Mononuclear Ru/Os Compounds with Hydrocarbon Ligands: Compounds with η1-Ligands;Comprehensive Organometallic Chemistry III;2007
3. Dichlorotris(triphenylphosphine)ruthenium(II) dichloromethane hemisolvate;Acta Crystallographica Section E Structure Reports Online;2005-05-31
4. Nonclassical vs Classical Metal···H3C−C Interactions: Accurate Characterization of a 14-Electron Ruthenium(II) System by Neutron Diffraction, Database Analysis, Solution Dynamics, and DFT Studies;Journal of the American Chemical Society;2004-04-08
5. Cyclometalated Phosphine-Based Pincer Complexes: Mechanistic Insight in Catalysis, Coordination, and Bond Activation;Chemical Reviews;2003-05-01
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