Formation of a tetranickel octacarbonyl cluster from the CO2 reaction of a zero-valent nickel monocarbonyl species
Author:
Affiliation:
1. Department of Chemistry
2. Korea Advanced Institute of Science and Technology (KAIST)
3. Daejeon 305-701
4. Republic of Korea
5. Center for Catalytic Hydrocarbon Functionalization
Abstract
The CO2 reaction of a nickel(0) complex involves multiple reaction pathways including tetranickel cluster formation via reductive disproportionation of CO2.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/QI/C6QI00011H
Reference38 articles.
1. M. Aresta , Carbon dioxide as Chemical Feedstock, Wiley-VCH, Weinhein, Germany, 2010
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3. Using carbon dioxide as a building block in organic synthesis
4. Structure, Function, and Mechanism of the Nickel Metalloenzymes, CO Dehydrogenase, and Acetyl-CoA Synthase
5. Reaction of (Cy3P)2Ni(H)(CH3) with carbon dioxide. Formation of an hydridonickel formate complex, HNi(O2CH)(Cy3P)2
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