Gas-phase structure and reactivity of the keto tautomer of the deoxyguanosine radical cation

Author:

Feketeová Linda12345,Chan Bun54674,Khairallah George N.12345,Steinmetz Vincent891011,Maître Philippe891011,Radom Leo54674,O'Hair Richard A. J.12345

Affiliation:

1. School of Chemistry and Bio21 Institute of Molecular Science and Biotechnology

2. The University of Melbourne

3. Parkville

4. Australia

5. ARC Centre of Excellence for Free Radical Chemistry and Biotechnology

6. School of Chemistry

7. University of Sydney

8. Laboratoire de Chimie Physique

9. Université Paris Sud

10. Orsay Cedex

11. France

Abstract

Gas-phase IR spectroscopy, ion–molecule reactions, collision-induced dissociation and computational chemistry in combination form a powerful tool to gain insights into the structure of one-electron oxidised guanine in DNA and its resultant chemistry.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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