Electron localization in a mixed-valence diniobium benzene complex-Reference-Cited by-同舟云学术

Electron localization in a mixed-valence diniobium benzene complex

Published:2015 Issue:2 Volume:6 Page:993-1003
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Gianetti Thomas L.¹²³⁴,Nocton Grégory⁵⁶⁷⁸⁹,Minasian Stefan G.¹⁰¹¹³⁴¹²,Kaltsoyannis Nikolas¹¹³¹⁴¹⁵,Kilcoyne A. L. David¹⁶¹¹³⁴,Kozimor Stosh A.¹²¹⁷¹⁸⁴,Shuh David K.¹⁰¹¹³⁴,Tyliszczak Tolek¹⁶¹¹³⁴,Bergman Robert G.¹²³⁴,Arnold John¹²³⁴

Affiliation:

1. Department of Chemistry

2. University of California

3. Berkeley

4. USA

5. Laboratoire de Chimie Moléculaire

6. CNRS

7. Ecole Polytechnique

8. 91128 Palaiseau

9. France

10. Chemical Sciences Division

11. Lawrence Berkeley National Laboratory

12. Chemistry Division

13. University College London

14. London

15. UK

16. Advanced Light Source

17. Los Alamos National Laboratory

18. Los Alamos

Abstract

One electron oxidation of a neutral diniobium benzene complex leads to a mixed-valence species. Single crystal X-ray diffraction, EPR, L_3,2-edge XANES, and DFT indicate that the unpaired electron is localized on one metal center.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C4SC02705A

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