Supramolecular copolymerization of hydrophobic and hydrophilic monomers in liquid crystalline media

Author:

Morishita Daiki1ORCID,Itoh Yoshimitsu12ORCID,Furukawa Ko3ORCID,Arai Noriyoshi4ORCID,Zhang Xu-Jie1,Aida Takuzo15ORCID

Affiliation:

1. Department of Chemistry and Biotechnology, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan

2. Precursory Research for Embryonic Science and Technology (PRESTO), Japan Science and Technology Agency (JST), 4-1-8 Honcho, Kawaguchi, Saitama 332-0012, Japan

3. Center for Coordination of Research Facilities, Institute for Research Administration, Niigata University, 8050 Ikarashi 2-no-cho, Nishi-ku, Niigata 950-2181, Japan

4. Department of Mechanical Engineering, Keio University, 3-14-1 Hiyoshi, Kohoku-ku, Yokohama 223-8522, Japan

5. Center for Emergent Matter Science (CEMS), RIKEN, 2-1 Hirosawa, Wako, Saitama 351-0198, Japan

Abstract

Two porphyrin-based monomers, C10P2H and TEGPCu, which have mutually incompatible side chains, undergo self-sorting supramolecular polymerization in a dilute solution, but can copolymerize to give a columnar LC phase in a mesogenic medium 5OCB.

Funder

Japan Society for the Promotion of Science

Japan Science and Technology Agency

Publisher

Royal Society of Chemistry (RSC)

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