Phonon bottleneck and long-lived excited states in π-conjugated pyrene hoop

Author:

Franklin-Mergarejo Ricardo1234,Nelson Tammie56789ORCID,Tretiak Sergei56789,Fernandez-Alberti Sebastian1234

Affiliation:

1. Universidad Nacional de Quilmes/CONICET

2. Roque Saenz Peña 352

3. Bernal

4. Argentina

5. Theoretical Division

6. Los Alamos National Laboratory

7. Los Alamos

8. New Mexico 87545

9. USA

Abstract

The phonon bottleneck in the nonradiative relaxation of a pyrene-based nanohoop slows down electronic relaxation and allows multi-channel relaxation.

Funder

Consejo Nacional de Investigaciones Científicas y Técnicas

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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