Silicon(<scp>iv</scp>) complexes of octaaryl-substituted porphyrazines and corrolazines: influence of macrocycle contraction on spectral-luminescence, acid–base, and redox properties-Reference-Cited by-同舟云学术

Silicon(iv) complexes of octaaryl-substituted porphyrazines and corrolazines: influence of macrocycle contraction on spectral-luminescence, acid–base, and redox properties

Published:2023 Issue:20 Volume:52 Page:6831-6840
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Rychikhina Ekaterina D.¹^ORCID,Ivanova Svetlana S.¹^ORCID,Novakova Veronika²^ORCID,Stuzhin Pavel A.¹^ORCID

Affiliation:

1. Institute of Macroheterocycles, Ivanovo State University of Chemistry and Technology, 153000 Ivanovo, Russia

2. Faculty of Pharmacy in Hradec Kralove, Charles University, Hradec Kralove, 500 05, Czech Republic

Abstract

Octaaryl-substituted Si(iv) corrolazine complexes, obtained by reductive ring contraction reaction of the appropriate SiPzAr8, exhibit high ability for single oxygen generation. The crucial role of acid in the Pz → Cz transformation is revealed.

Funder

Grantová Agentura České Republiky

Russian Foundation for Basic Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT00319A

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