Confluence of disparate carbido chemistries: [WRuAu2(μ-C)2Cl2(CO)2(PCy3)2(Tp*)]
Author:
Affiliation:
1. Department of Chemistry
2. University of Copenhagen
3. Universitetsparken 5
4. Denmark
5. Research School of Chemistry
6. Australian National University
7. Canberra
8. Australia
Abstract
The reaction of [Ru(CAuCl)Cl2(PCy3)2] with [W(CSnnBu3)(CO)2(Tp*)] (obtained from [W(CBr)(CO)2(Tp*)], nBuLi and ClSnnBu3) affords the heterotetrametallic bis(carbido) complex [WRuAu2(μ-C)2Cl3(CO)2(PCy3)2(Tp*)] in which the two distinct μ-carbido ligands adopt linear and T-shaped geometry at carbon.
Funder
Australian Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT03851A
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