Satellite ligand effects on magnetic exchange in dimers. A structural, magnetic and theoretical investigation of Cu2L2X4 (L = methylisothiazolinone and X = Cl−, Br−)-Reference-Cited by-同舟云学术

Satellite ligand effects on magnetic exchange in dimers. A structural, magnetic and theoretical investigation of Cu₂L₂X₄ (L = methylisothiazolinone and X = Cl⁻, Br⁻)

Published:2023 Issue:13 Volume:25 Page:9176-9187
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Coetzee Stefan¹,Turnbull Mark M.²^ORCID,Landee Christopher P.³,Monroe Jeffrey C.²,Deumal Mercè⁴^ORCID,Novoa Juan. J.⁵,Rademeyer Melanie¹^ORCID

Affiliation:

1. Department of Chemistry, University of Pretoria, Pretoria, 0002, South Africa

2. Carlson School of Chemistry and Biochemistry, Clark University, 950 Main St., Worcester, Massachusetts, 01610, USA

3. Department of Physics, Clark University, 950 Main St., Worcester, Massachusetts, 01610, USA

4. Serra-Húnter Fellow, Departament de Ciència de Materials i Química Física and IQTCUB, Facultat de Química, Universitat de Barcelona, Martí i Franquès 1, 08028, Barcelona, Spain

5. Departament de Ciència de Materials i Química Física and IQTCUB, Facultat de Química, Universitat de Barcelona, Martí i Franquès 1, 08028, Barcelona, Spain

Abstract

The orientation of the terminal/satellite L ligands in stacked-dimer Cu2X4L2 polymers is shown to affect the magnetic exchange in and between dimers. This information introduces an additional design tool to tune the magnetic exchange from AFM to FM.

Funder

Ministerio de Economía y Competitividad

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D2CP05629A

Reference40 articles.

1. Electrical conductive coordination polymers

2. Ferromagnetic dimer interactions in Cu2Cl4(CH3CN)2

3. Synthesis, structure, and magnetic properties of bis(monosubstituted-pyrazine)dihalocopper(ii)

4. Recent Developments in Low‐Dimensional Copper(II) Molecular Magnets

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