CO2-tuned highly selective reduction of formamides to the corresponding methylamines-Reference-Cited by-同舟云学术

CO2-tuned highly selective reduction of formamides to the corresponding methylamines

Published:2021 Issue:19 Volume:23 Page:7534-7538
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Guo Zhiqiang¹^ORCID,Pang Tengfei²,Yan Leilei²,Wei Xuehong¹,Chao Jianbin¹^ORCID,Xi Chanjuan³^ORCID

Affiliation:

1. Scientific Instrument Center, Shanxi University, Taiyuan, 030006, P.R. China

2. School of Chemistry and Chemical Engineering, Shanxi University, Taiyuan, 030006, P.R. China

3. MOE Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology, Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China

Abstract

An efficient, CO2-tuned and highly selective C–O bond cleavage of N-methylated formanilides with NaBH4 has been achieved. Notably, when using N2 as reaction atmosphere, the reaction gave N-methylaniline as major product via C–N bond hydrogenolysis.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Shanxi Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/GC/D1GC02815D

Reference56 articles.

1. Chemoselective reduction of carboxamides

2. Mild Hydrogenation of Amides to Amines over a Platinum-Vanadium Bimetallic Catalyst