The role of polysulfide dianions and radical anions in the chemical, physical and biological sciences, including sulfur-based batteries

Author:

Steudel Ralf1234ORCID,Chivers Tristram5678ORCID

Affiliation:

1. Institute of Chemistry

2. Technical University Berlin

3. D-10623 Berlin

4. Germany

5. Department of Chemistry

6. The University of Calgary

7. Calgary

8. Canada

Abstract

Polysulfide dianions and radical anions play a crucial role in biological chemistry, geochemical processes, alkali metal–sulfur batteries, organic syntheses, coordination chemistry, and materials sciences.

Funder

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference232 articles.

1. Solid Sulfur Allotropes Sulfur Allotropes

2. I. Krossing , in Handbook of Chalcogen Chemistry: New Perspectives in Sulfur, Selenium and Tellurium , ed. F. A. Devillanova and W.-W. du Mont , RSC Publishing , 2nd edn, 2013 , vol. 1, ch. 7.1, pp. 349–381

3. The identification of S5+ as a paramagnetic species in sulfur-oleum solutions by electron spin resonance

4. Evidence for the Blue 10π S62+ Dication in Solutions of S8(AsF6)2: A Computational Study Including Solvation Energies

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