Heterocyclic bismuth(iii) compounds with transannular N→Bi interactions as catalysts for the oxidation of thiophenol to diphenyldisulfide

Author:

Toma Ana M.12345,Raţ Ciprian I.12345ORCID,Pavel Octavian D.678910ORCID,Hardacre Christopher1112131415ORCID,Rüffer Tobias1617181920ORCID,Lang Heinrich1617181920,Mehring Michael16171920ORCID,Silvestru Anca12345ORCID,Pârvulescu Vasile I.678910ORCID

Affiliation:

1. Supramolecular Organic and Organometallic Chemistry Centre

2. Faculty of Chemistry & Chemical Engineering

3. Chemistry Department

4. Babes-Bolyai University

5. RO-400028 Cluj-Napoca

6. Faculty of Chemistry

7. Department of Organic Chemistry

8. Biochemistry and Catalysis

9. University of Bucharest

10. 030018 Bucharest

11. Queen's University Belfast

12. The QUILL Centre/School of Chemistry and Chemical Engineering

13. Belfast

14. UK

15. The University of Manchester

16. Technische Universität Chemnitz

17. Institut für Chemie

18. Anorganische Chemie

19. D-09107 Chemnitz

20. Germany

Abstract

Aerial oxidation of thiophenol to diphenyl disulfide proceeds with high reaction rates, total conversion and selectivity in ionic liquids by using diorganobismuth(iii) catalysts.

Funder

Consiliului National al Cercetarii Stiintifice din Invatamantul Superior

Deutscher Akademischer Austauschdienst

Deutsche Forschungsgemeinschaft

European Regional Development Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Reference120 articles.

1. Efficient and Convenient Oxidation of Thiols to Symmetrical Disulfide with Silica–PCl5/NaNO2in Water

2. An Introduction to Organosulfur Chemistry, ed. R. J. Cremlyn, Wiley & Sons, New York, 1996

3. Aerobic oxidation of thiols to disulfides using iron metal–organic frameworks as solid redox catalysts

4. P. C. Jocelyn , Biochemistry of the Thiol Group, Academic Press, New York, 1977

5. Total synthesis of (+)-leinamycin

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