Transition metal-catalyzed redox isomerization of codeine and morphine in water-Reference-Cited by-同舟云学术

Transition metal-catalyzed redox isomerization of codeine and morphine in water

Published:2014 Issue:74 Volume:4 Page:39519-39522
ISSN:2046-2069
Container-title:RSC Adv.
language:en
Short-container-title:RSC Adv.

Author:

Gómez Antonio Bermejo¹²³⁴⁵,Holmberg Pär⁶⁷,Bäckvall Jan-E.¹²³⁴⁵,Martín-Matute Belén¹²³⁴⁵

Affiliation:

1. Department of Organic Chemistry

2. Arrhenius Laboratory

3. Stockholm University

4. Stockholm, Sweden

5. Berzelii Center EXSELENT

6. Cambrex Karlskoga AB

7. Karlskoga, Sweden

Abstract

A water-soluble rhodium complex formed from commercially available [Rh(COD)(CH₃CN)₂]BF₄ and 1,3,5-triaza-7-phosphaadamantane (PTA) catalyzes the isomerization of both codeine and morphine into hydrocodone and hydromorphone in water with very high efficiency.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/RA/C4RA07735K

Reference41 articles.

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2. International Narcotics Control Board (INCB) , World's totals of estimates from 2009 to 2014: http://www.incb.org/documents/Narcotic-Drugs/Technical-Publications/2013/Annex_2_EFS.pdf, (accessed in March, 2014)

3. Towards an Efficient Preparation of Hydromorphone

4. A Rapid, Nearly Quantitative Conversion of Codeine to Hydrocodone

5. Studies on regioselective hydrogenation of thebaine and its conversion to hydrocodone

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