It's all about Me: methyl-induced control of coordination stereochemistry by a flexible tridentate N,C,N′ ligand-Reference-Cited by-同舟云学术

It's all about Me: methyl-induced control of coordination stereochemistry by a flexible tridentate N,C,N′ ligand

Published:2014 Issue:7 Volume:43 Page:2971-2978
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Kariuki Benson M.¹²³,Platts James A.¹²³,Newman Paul D.⁴¹²³

Affiliation:

1. School of Chemistry

2. Cardiff University

3. Cardiff CF10 3AT, UK

4. Cardiff Catalysis Institute

Abstract

The introduction of a single methyl group on one of the chelate arms of a dipyridyl-NHC ligand has been achieved stereoselectively and the resultant tridentate ligand (S-LMe) coordinated to Rh(i), Ir(i) and Ni(ii) to give single diastereomers.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C3DT52841C

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