Reactivity of a dihydroboron species: synthesis of a hydroborenium complex and an expedient entry into stable thioxo- and selenoxo-boranes
Author:
Affiliation:
1. Department of Chemical Sciences
2. Indian Institute of Science Education and Research Mohali
3. Mohali 140306
4. India
Abstract
Oxidative insertion of sulfur or selenium into the B–H bonds, of bis(phosphinimino)amide stabilized dihydroboron species, followed by H2S or H2Se evolution leads to a facile access to stable thioxo- and selenoxo-boranes.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT02788H
Reference39 articles.
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5. Oxoboryl Complexes: Boron−Oxygen Triple Bonds Stabilized in the Coordination Sphere of Platinum
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