Metal–ligand cooperative transformation of alkyl azide to isocyanate occurring at a Co

Metal–ligand cooperative transformation of alkyl azide to isocyanate occurring at a Co–Si moiety

Published:2021 Issue:26 Volume:57 Page:3219-3222
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

So Jongho¹²³⁴^ORCID,Kim Seji¹⁵⁶⁴,Cho Kyung-Bin¹⁷⁸⁴^ORCID,Lee Yunho¹⁵⁶⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Korea Advanced Institute of Science and Technology (KAIST)

3. Daejeon 34141

4. Republic of Korea

5. Seoul National University

6. Seoul 08826

7. Jeonbuk National University

8. Jeonju 54896

Abstract

At a cobalt(i)-silyl moiety, a nitrene group was inserted into the Co–Si bond and extracted upon carbonylation to generate AdNCO.

Funder

National Research Foundation of Korea

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D0CC08012H

Reference37 articles.

1. Carbodiimide Synthesis via Ti-Catalyzed Nitrene Transfer from Diazenes to Isocyanides

2. Synthesis, Structure, and Reactivity of Low-Spin Cobalt(II) Imido Complexes [(Me3P)3Co(NAr)]

3. Catalytic Formation of Asymmetric Carbodiimides at Mononuclear Chromium(II/IV) Bis(alkoxide) Complexes

4. β-Diketiminato Nickel Imides in Catalytic Nitrene Transfer to Isocyanides

5. Nitrene Chemistry in Organic Synthesis: Still in Its Infancy?

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