Metal triflate promoted synthesis of naphthalenes
Author:
Affiliation:
1. Department of Medicinal and Applied Chemistry
2. Kaohsiung Medical University Hospital
3. Kaohsiung Medical University
4. Kaohsiung 80708
5. Taiwan
Abstract
A synthetic route to derive the skeleton of naphthalenes starting with isovanillin is described with modest total yields via the key transformation of metal triflate-mediated intramolecular benzannulation of o-formyl or o-benzoyl allylbenzenes in MeNO2 at rt.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/RA/C7RA04960A
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