Rhodium(<scp>iii</scp>)-catalyzed oxidative annulation of<i>N</i>-arylbenzamidines with maleimides<i>via</i>dual C

Rhodium(iii)-catalyzed oxidative annulation ofN-arylbenzamidines with maleimidesviadual C–H activation

Published:2023 Issue:8 Volume:21 Page:1719-1724
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Sankaram G. Siva¹²,Sahoo Tanmoy¹²,Sridhar B.³^ORCID,Subba Reddy B. V.¹^ORCID

Affiliation:

1. Fluoro-Agrochemicals, CSIR-Indian Institute of Chemical Technology, Hyderabad, India

2. Academy of Scientific and Innovative Research (AcSIR), Ghaziabad, UP, India

3. Laboratory of X-ray Crystallography, CSIR-Indian Institute of Chemical Technology, Hyderabad, India

Abstract

An oxidative annulation ofN-arylbenzimidamides with maleimides in the presence of [Cp*RhCl2]2provides the corresponding benzo[4,5]imidazo[2,1-a]pyrrolo[3,4-c]isoquinoline-1,3(2H)-diones.

Funder

Council of Scientific and Industrial Research, India

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/OB/D2OB01972H

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