Efficient preparation of carbamates by Rh-catalysed oxidative carbonylation: unveiling the role of the oxidant-Reference-Cited by-同舟云学术

Efficient preparation of carbamates by Rh-catalysed oxidative carbonylation: unveiling the role of the oxidant

Published:2017 Issue:2 Volume:53 Page:404-407
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Iturmendi Amaia¹²³⁴^ORCID,Iglesias Manuel¹²³⁴^ORCID,Munárriz Julen⁵⁶³⁴^ORCID,Polo Victor⁵⁶³⁴^ORCID,Pérez-Torrente Jesús J.¹²³⁴^ORCID,Oro Luis A.¹²³⁴⁷^ORCID

Affiliation:

1. Departamento Química Inorgánica – ISQCH

2. Universidad de Zaragoza – CSIC

3. 50009 Zaragoza

4. Spain

5. Departamento Química Física – Instituto de Biocomputación y Física de Sistemas Complejos (BIFI)

6. Universidad de Zaragoza

7. King Fahd University of Petroleum & Minerals (KFUPM)

Abstract

A Rh(i)-catalysed three-component reaction allows access to carbamates from amines or imines under mild conditions in the presence of Oxone, which plays a dual role as a base and an oxidant.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CC/C6CC09133D

Reference51 articles.

1. Organic Carbamates in Drug Design and Medicinal Chemistry

2. Selective cleavage of the allyl and (allyloxy)carbonyl groups through palladium-catalyzed hydrostannolysis with tributyltin hydride. Application to the selective protection-deprotection of amino acid derivatives and in peptide synthesis

3. On the use of silylated nucleophiles in the palladium catalysed deprotection of allylic carboxylates and carbamates.

4. Side reactions and cadmium catalysed removal of the trichloro-ethoxycarbonyl (troc) protecting group.

5. T. A. Unger , in Pesticides Synthesis Book, ed. W. Andrew, Noyes Publications, New Jersey, 1996

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