Evolution of a ‘privileged’ P-alkene ligand: added planar chirality beats BINOL axial chirality in catalytic asymmetric C–C bond formation-Reference-Cited by-同舟云学术

Evolution of a ‘privileged’ P-alkene ligand: added planar chirality beats BINOL axial chirality in catalytic asymmetric C–C bond formation

Published:2023 Issue:97 Volume:59 Page:14451-14454
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Leinauer Luisa¹,Parla Giorgio¹,Messelbeger Julian¹,Herrera Alberto¹,Heinemann Frank W.¹,Langer Jens¹^ORCID,Chuchelkin Ilya²^ORCID,Grasruck Alexander¹,Frieß Sibylle¹,Chelouan Ahmed³,Gavrilov Konstantin²^ORCID,Dorta Romano¹^ORCID

Affiliation:

1. Department of Chemistry and Pahrmacy, Chair of Inorganic and General Chemistry, Friedrich Alexander Universität Erlangen–Nürnberg, Egerlandstraße 1, 91058 Erlangen, Germany

2. Department of Chemistry, Ryazan State University Named after S. Yesenin, 46 Svoboda Street, 390000 Ryazan, Russian Federation

3. Department of Chemistry, Abdelmalek Essaadi University, B.P. 2121, 39, Hannech II, 93002 Tétouan, Morocco

Abstract

Planar chirality is introduced in a ‘privileged’ P-alkene phosphoramidite ligand and shown to overwhelm the chirality of the BINOL auxiliary.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC04972H

Reference31 articles.

1. Phosphoramidites: Privileged Ligands in Asymmetric Catalysis

2. Iridium-Catalyzed Synthesis of Primary Allylic Amines from Allylic Alcohols: Sulfamic Acid as Ammonia Equivalent

3. Chiral Dibenzazepine-Based P-Alkene Ligands and Their Rhodium Complexes: Catalytic Asymmetric 1,4 Additions to Enones

4. Hemilabile P-Alkene Ligands in Chiral Rhodium and Copper Complexes: Catalytic Asymmetric 1,4 Additions to Enones. 2,

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