The role of transesterifications in reversible polycondensations and a reinvestigation of the Jacobson–Beckmann–Stockmayer experiments-Reference-Cited by-同舟云学术

The role of transesterifications in reversible polycondensations and a reinvestigation of the Jacobson–Beckmann–Stockmayer experiments

Published:2022 Issue:9 Volume:13 Page:1177-1185
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Kricheldorf Hans R.¹,Weidner Steffen M.²^ORCID,Falkenhagen Jana²^ORCID

Affiliation:

1. Universität Hamburg, Institut für Technische und Makromolekulare Chemie, Bundesstrasse. 45, D-20145 Hamburg, Germany

2. Bundesanstalt für Materialforschung und -prüfung, BAM 6.3, Richard-Willstätter-Strasse 11, D-12489 Berlin, Germany

Abstract

Strong protic acids catalyze intermolecular transesterification in reversible polyester syntheses even at low temperatures (109 °C), an important aspect not considered in the original Jacobson–Stockmayer theory of reversible polycondensations.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2022/PY/D1PY01679B

Reference15 articles.

1. Polymerization.

2. Fundamental Principles of Condensation Polymerization.

3. Intramolecular Reaction in Polycondensations. II. Ring‐Chain Equilibrium in Polydecamethylene Adipate

4. Intramolecular Reaction in Polycondensations. I. The Theory of Linear Systems

5. J. A.Semlyen , in Large Ring Molecules , ed. J. A. Semlyen , J. Wiley & Sons , Chichester , 1996 , ch. 1

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