Bismuth⋯π arene versus bismuth⋯halide coordination in heterocyclic diorganobismuth(iii) compounds with transannular N→Bi interaction-Reference-Cited by-同舟云学术

Bismuth⋯π arene versus bismuth⋯halide coordination in heterocyclic diorganobismuth(iii) compounds with transannular N→Bi interaction

Published:2017 Issue:12 Volume:46 Page:3953-3962
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Toma Ana Maria¹²³⁴⁵,Pop Alexandra¹²³⁴⁵,Silvestru Anca¹²³⁴⁵^ORCID,Rüffer Tobias⁶⁷⁸⁹¹⁰^ORCID,Lang Heinrich⁶⁷⁸⁹¹⁰,Mehring Michael⁶⁷¹¹⁹¹⁰

Affiliation:

1. Supramolecular Organic and Organometallic Chemistry Centre

2. Faculty of Chemistry & Chemical Engineering

3. Chemistry Department

4. Babes-Bolyai University

5. RO-400028 Cluj-Napoca

6. Technische Universität Chemnitz

7. Institut für Chemie

8. Anorganische Chemie

9. D-09107 Chemnitz

10. Germany

11. Koordinationschemie

Abstract

The hypervalent diorganobismuth(iii) halides of type [RCH₂N(CH₂C₆H₄)₂]BiX, (R = Ph, Bz, and MeO) show a strong tendency to associate either by Bi⋯X or by Bi⋯π arene secondary interactions.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT00188F

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