N-Heterocyclic carbene stabilized parent sulfenyl, selenenyl, and tellurenyl cations (XH+, X = S, Se, Te)

Author:

Liu Liu Leo1234ORCID,Zhu Diya1234,Cao Levy L.1234,Stephan Douglas W.1234ORCID

Affiliation:

1. Department of Chemistry

2. University of Toronto

3. Toronto

4. Canada M5S 3H6

Abstract

NHC-stabilized parent sulfenyl (H–S+), selenenyl (H–Se+) and tellurenyl (H–Te+) cations have been achieved by treatment of NHC chalcogen adducts with trifluoromethanesulfonic acid.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference59 articles.

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2. S.Patai and Z.Rappoport , The chemistry of organic selenium and tellurium compounds , John Wiley & Sons , 1986

3. Reactive p-block cations stabilized by weakly coordinating anions

4. F. A.Devillanova and W.-W.Du Mont , Handbook of chalcogen chemistry: new perspectives in sulfur, selenium and tellurium , Royal Society of Chemistry , 2013

5. P.Wenthold , in Nitrenes and Nitrenium Ions , Wiley Series on Reactive Intermediates in Chemistry and Biochemistry, ed. D. E. Falvey and A. D. Gudmundsdottir , Wiley Online Library , 2014 , vol. 6

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