Gyroscope like molecules consisting of trigonal or square planar osmium rotators within three-spoked dibridgehead diphosphine stators: syntheses, substitution reactions, structures, and dynamic properties-Reference-Cited by-同舟云学术

Gyroscope like molecules consisting of trigonal or square planar osmium rotators within three-spoked dibridgehead diphosphine stators: syntheses, substitution reactions, structures, and dynamic properties

Published:2016 Issue:16 Volume:45 Page:7131-7147
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Fiedler Tobias¹²³⁴⁵^ORCID,Bhuvanesh Nattamai¹²³⁴,Hampel Frank⁵⁶⁷⁸,Reibenspies Joseph H.¹²³⁴,Gladysz John A.¹²³⁴

Affiliation:

1. Department of Chemistry

2. Texas A&M University

3. College Station

4. USA

5. Institut für Organische Chemie and Interdisciplinary Center for Molecular Materials

6. Friedrich-Alexander-Universität Erlangen-Nürnberg

7. 91054 Erlangen

8. Germany

Abstract

The OsL_y moieties of the title complexes undergo rapid rotation within the diphosphine cages when L is restricted to Cl, Br, CO, H, and Me.

Funder

Division of Chemistry

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT00692B

Reference66 articles.

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