The effect of water on gold supported chiral graphene nanoribbons: rupture of conjugation by an alternating hydrogenation pattern

Author:

Berdonces-Layunta Alejandro12,Matěj Adam345ORCID,Jiménez-Martín Alejandro346ORCID,Lawrence James12,Mohammed Mohammed S. G.12ORCID,Wang Tao12ORCID,Mallada Benjamin345ORCID,de la Torre Bruno4ORCID,Martínez Adrián7,Vilas-Varela Manuel7,Nieman Reed8ORCID,Lischka Hans8,Nachtigallová Dana910,Peña Diego7ORCID,Jelínek Pavel34,de Oteyza Dimas G.1211ORCID

Affiliation:

1. Donostia International Physics Center, 20018 San Sebastian, Spain

2. Centro de Fisica de Materiales, 20018 San Sebastian, Spain

3. Institute of Physics, Czech Academy of Sciences, 16200 Prague, Czech Republic

4. Regional Centre of Advanced Technologies and Materials, Czech Advanced Technology and Research Institute (CATRIN), Palacky University, 783 71 Olomouc, Czech Republic

5. Department of Physical Chemistry, Faculty of Science, Palacky University, 779 00 Olomouc, Czech Republic

6. Faculty of Nuclear Sciences and Physical Engineering, Czech Technical University in Prague, Brehova 7, Prague 1 115 19, Czech Republic

7. Centro Singular de Investigacion en Quimica Bioloxica e Materiais Moleculares (CiQUS), and Departamento de Quimica Organica, Universidade de Santiago de Compostela, 15705 Santiago de Compostela, Spain

8. Department of Chemistry and Biochemistry, Texas Tech University, Lubbock, TX 79409-1061, USA

9. Institute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, 16000 Prague, Czech Republic

10. IT4Innovations, VSB-Technical University of Ostrava, 17. listopadu 2172/15, Ostrava-Poruba 70800, Czech Republic

11. Nanomaterials and Nanotechnology Research Center (CINN), CSIC-UNIOVI-PA, 33940 El Entrego, Spain

Abstract

The effect of water on gold-supported chiral graphene nanoribbons has been studied. The results show a spontaneous hydrogenation of the ribbons with a well-defined periodic pattern, even at room temperature and with no other external activation.

Funder

European Regional Development Fund

Xunta de Galicia

Agencia Estatal de Investigación

Grantová Agentura Ceské Republiky

Ministerstvo Školství, Mládeže a Telovýchovy

Univerzita Palackého v Olomouci

National Science Foundation

European Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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