1,4-Bis(2′-pyridylethynyl)benzene as a ligand in heteronuclear gold–thallium complexes. Influence of the ancillary ligands on their optical properties

Author:

Arca Massimiliano1234,Donamaría Rocío56789,Gimeno M. Concepción1011121314,Lippolis Vito1234,López-de-Luzuriaga José M.56789,Manso Elena56789,Monge Miguel56789,Olmos M. Elena56789

Affiliation:

1. Dipartimento di Scienze Chimiche e Geologiche

2. Università degli Studi di Cagliari

3. 09042 Monserrato

4. Italy

5. Departamento de Química

6. Universidad de La Rioja

7. Centro de Investigación en Síntesis Química (CISQ)

8. Complejo Científico-Tecnológico

9. 26006 Logroño

10. Departamento de Química Inorgánica

11. Instituto de Ciencia de Materiales de Aragón

12. Universidad de Zaragoza-CSIC

13. 50009 Zaragoza

14. Spain

Abstract

Complexes [{Au(C6Cl5)2}Tl(L)]n(luminescent) and [{Au(C6F5)2}2Tl2(L)2]n(non-luminescent) (L = 1,4-bis(2′-pyridylethynyl)benzene) have been synthesized and their crystal structures and photophysical properties have been studied.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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