A comprehensive test set of epoxidation rate constants for iron(iv)–oxo porphyrin cation radical complexes-Reference-Cited by-同舟云学术

A comprehensive test set of epoxidation rate constants for iron(iv)–oxo porphyrin cation radical complexes

Published:2015 Issue:2 Volume:6 Page:1516-1529
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Sainna Mala A.¹²³⁴,Kumar Suresh⁵⁶⁷⁸⁹,Kumar Devesh⁵⁶⁷⁸⁹,Fornarini Simonetta¹⁰¹¹¹²¹³,Crestoni Maria Elisa¹⁰¹¹¹²¹³,de Visser Sam P.¹²³⁴

Affiliation:

1. Manchester Institute of Biotechnology and School of Chemical Engineering and Analytical Science

2. The University of Manchester

3. Manchester M1 7DN

4. UK

5. Department of Applied Physics

6. School for Physical Sciences

7. Babasaheb Bhimrao Ambedkar University

8. Lucknow 226 025

9. India

10. Dipartimento di Chimica e Tecnologie del Farmaco

11. Università di Roma “La Sapienza”

12. Roma

13. Italy

Abstract

Trends in oxygen atom transfer to Compound I of the P450 models with an extensive test set have been studied and show a preferred regioselectivity of epoxidation over hydroxylation in the gas-phase for the first time.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C4SC02717E

Reference102 articles.

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2. The bioinorganic chemistry of iron in oxygenases and supramolecular assemblies

3. Cytochrome P450: Structure, Mechanism and Biochemistry, ed. P. R. Ortiz de Montellano, Kluwer Academic/Plenum Publishers, New York, 3rd edn, 2004

4. Structure and Chemistry of Cytochrome P450

5. Handbook of Porphyrin Science, ed. K. M. Kadish, K. M. Smith and R. Guilard, World Scientific, New Jersey, 2010

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