o-Quinone methide with overcrowded olefin component as a dehydridation catalyst under aerobic photoirradiation conditions-Reference-Cited by-同舟云学术

o-Quinone methide with overcrowded olefin component as a dehydridation catalyst under aerobic photoirradiation conditions

Published:2021 Issue:8 Volume:12 Page:2778-2783
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Uraguchi Daisuke¹²³⁴^ORCID,Kato Kohsuke⁵⁶⁷⁸⁹^ORCID,Ooi Takashi⁵⁶⁷⁸⁹^ORCID

Affiliation:

1. Institute for Catalysis

2. Hokkaido University

3. Sapporo 001-0021

4. Japan

5. Institute of Transformative Bio-Molecules (WPI-ITbM)

6. Department of Molecular and Macromolecular Chemistry

7. Graduate School of Engineering

8. Nagoya University

9. Nagoya 464-8601

Abstract

An o-quinone methide (o-QM) featuring an overcrowded olefinic framework is introduced, which exhibits dehydridation activity owing to its enhanced zwitterionic character, particularly through photoexcitation.

Funder

Japan Society for the Promotion of Science

Nagoya University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D0SC06240E

Reference34 articles.

1. Contemporary Carbocation Chemistry: Applications in Organic Synthesis

2. Quinone‐Catalyzed Selective Oxidation of Organic Molecules

3. Intramolecular Cyclizations of Vinyl-Substituted N,N-Dialkyl Arylamines Enabled by Borane-Assisted Hydride Transfer

4. Recent Advances in Direct Catalytic Asymmetric Transformations under Proton-Transfer Conditions

5. Oxidation of ethers via hydride abstraction: a new procedure for selective oxidation of primary, secondary diols at the secondary position

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