Unique selectivity reversal between Am<sup>3+</sup> and Eu<sup>3+</sup> ions by incorporation of alkyl branching in diglycolamide derivatives: DFT validation of experimental results-Reference-Cited by-同舟云学术

Unique selectivity reversal between Am³⁺ and Eu³⁺ ions by incorporation of alkyl branching in diglycolamide derivatives: DFT validation of experimental results

Published:2022 Issue:38 Volume:46 Page:18543-18550
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Bhattacharyya Arunasis¹^ORCID,Kanekar Avinash S.¹,Egberink Richard J. M.²,Verboom Willem²^ORCID,Huskens Jurriaan²^ORCID,Mohapatra Prasanta K.¹^ORCID

Affiliation:

1. Radiochemistry Division, Bhabha Atomic Research Centre, Trombay, Mumbai, 400085, India

2. Molecular Nanofabrication Group, Department of Molecules & Materials, MESA+ Institute for Nanotechnology, University of Twente, P. O. Box 217, 7500 AE, Enschede, The Netherlands

Abstract

Incorporation of alkyl branching at α position in DGA derivative showed reversal of selectivity between Am3+ and Eu3+ which was explained using luminescence spectroscopic and DFT calculations.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NJ/D2NJ03007A

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