Molecular conductors from bis(ethylenedithio)tetrathiafulvalene with tris(oxalato)gallate and tris(oxalato)iridate

Author:

Blundell Toby J.1ORCID,Morritt Alexander L.1ORCID,Rusbridge Elizabeth K.1,Quibell Luke1,Oakes Jakob1,Akutsu Hiroki2ORCID,Nakazawa Yasuhiro2,Imajo Shusaku3,Kadoya Tomofumi4ORCID,Yamada Jun-ichi4,Coles Simon J.5ORCID,Christensen Jeppe5,Martin Lee1ORCID

Affiliation:

1. School of Science and Technology, Nottingham Trent University, Clifton Lane, Clifton, Nottingham, NG11 8NS, UK

2. Department of Chemistry, Graduate School of Science, Osaka University, 1-1 Machikaneyama-cho, Toyonaka, Osaka 560-0043, Japan

3. The Institute for Solid State Physics, The University of Tokyo, Kashiwa, Chiba 277-8581, Japan

4. Graduate School of Material Science, University of Hyogo, Kamigori-cho, Ako-gun, Hyogo, 678-1297, Japan

5. School of Chemistry, Faculty of Natural and Environmental Sciences, University of Southampton, Highfield, Southampton, SO17 1BJ, UK

Abstract

Six new BEDT-TTF salts with tris(oxalato)gallate or -iridate anions including two new superconductors β′′-(BEDT-TTF)4[(H3O)Ga(C2O4)3]·guest (bromobenzene or iodobenzene) and a novel 5 : 1 metal–insulator β′′-(BEDT-TTF)5Ir(C2O4)3 ethanol.

Funder

Leverhulme Trust

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Chemistry (miscellaneous)

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