An unexpected interfacial Mo-rich phase in 2D molybdenum disulfide and 3D gold heterojunctions

Author:

Wang Mengjia1,Luo Ruichun2,Liu Yuxin3,Zhao Xiaoran1,Zhuang Xiaodong4ORCID,Xu Wen Wu3ORCID,Chen Mingwei5ORCID,Liu Pan1ORCID

Affiliation:

1. Shanghai Key Laboratory of Advanced High-temperature Materials and Precision Forming, State Key Laboratory of Metal Matrix Composites, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, P. R. China

2. School of Physical Sciences and CAS Key Laboratory of Vacuum Physics, University of Chinese Academy of Sciences, Beijing 100049, China

3. Department of Physics, School of Physical Science and Technology, Ningbo University, Ningbo 315211, China

4. School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, P. R. China

5. Department of Materials Science and Engineering, Johns Hopkin University, Baltimore, MD 21218, USA

Abstract

We found a Mo-rich phase during thermal sulfidation Mo–Au surface alloy to MoS2 in S-poor environment, and the Mo-rich phase preferentially nucleates and grows between outmost MoS2 and 3D Au substrate which possesses copious surface steps and kinks.

Funder

Program for Professor of Special Appointment (Eastern Scholar) at Shanghai Institutions of Higher Learning

Natural Science Foundation of Shanghai

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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