New monoclinic ruthenium dioxide with highly selective hydrogenation activity

Author:

Yang Hee Jung1ORCID,Redington Morgan2ORCID,Miller Daniel P.3ORCID,Zurek Eva2ORCID,Kim Minseob4,Yoo Choong-Shik4,Lim Soo Yeon5ORCID,Cheong Hyeonsik5ORCID,Chae Seen-Ae6,Ahn Docheon7ORCID,Hur Nam Hwi1ORCID

Affiliation:

1. Department of Chemistry, Sogang University, Seoul 04107, Korea

2. Department of Chemistry, State University of New York at Buffalo, Buffalo, NY 14260, USA

3. Department of Chemistry, Hofstra University, Hempstead, NY 11549, USA

4. Department of Chemistry, Institute for Shock Physics, Washington State University, Pullman, WA 99164, USA

5. Department of Physics, Sogang University, Seoul 04107, Korea

6. Western Seoul Center, Korea Basic Science Institute, Seoul 03759, Korea

7. Beamline Research Division, Pohang Accelerator Laboratory, Pohang University of Science and Technology, Pohang 37673, Korea

Abstract

HxRuO2 acts as a standalone catalyst exhibiting selective hydrogenation under mild conditions. Mobile protons embedded in the oxide lattice play an important role in stabilizing the distorted structure, and facile proton dynamics is key to improving catalytic properties.

Funder

National Research Foundation of Korea

National Science Foundation

Korea Basic Science Institute

National Nuclear Security Administration

Korea Institute of Energy Technology Evaluation and Planning

Hofstra University

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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