A 4-cyanobenzene-ethylenedithio-TTF electron donor and its (1 : 1) triiodide radical cation salt; isomer effects in C–N⋯H

A 4-cyanobenzene-ethylenedithio-TTF electron donor and its (1 : 1) triiodide radical cation salt; isomer effects in C–N⋯H–C interactions

Published:2019 Issue:4 Volume:21 Page:637-647
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Lopes Gonçalo¹²³⁴⁵,da Gama Vasco¹²³⁴⁵^ORCID,Belo Dulce¹²³⁴⁵^ORCID,Simão Dulce⁶²³⁷⁵^ORCID,Santos Isabel Cordeiro¹²³⁴⁵^ORCID,Almeida Manuel¹²³⁴⁵^ORCID,Rabaça Sandra¹²³⁴⁵^ORCID

Affiliation:

1. C2TN, Centro de Ciências e Tecnologias Nucleares

2. Instituto Superior Técnico

3. Universidade de Lisboa

4. 2695-066 Bobadela LRS

5. Portugal

6. Centro de Química Estrutural

7. P-1049-001 Lisboa

Abstract

A new isomer of the dissymmetric TTF derivative, 4-cyanobenzene-ethylenedithio-tetrathiafulvalene (4-CNB-EDT-TTF) (1), was prepared and compared with the previously reported 5-CNB-EDT-TTF.

Funder

Fundação para a Ciência e a Tecnologia

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CE/C8CE01967C

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