Mechanistic study on the reductive elimination of (aryl)(fluoroaryl)palladium complexes: a key step in regiospecific dehydrogenative cross-coupling-Reference-Cited by-同舟云学术

Mechanistic study on the reductive elimination of (aryl)(fluoroaryl)palladium complexes: a key step in regiospecific dehydrogenative cross-coupling

Published:2024 Issue:32 Volume:53 Page:13340-13347
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Iida Tomoki¹,Sato Ryota¹,Yoshigoe Yusuke²^ORCID,Kanbara Takaki¹^ORCID,Kuwabara Junpei¹³^ORCID

Affiliation:

1. Institute of Pure and Applied Sciences, University of Tsukuba 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8573, Japan

2. Department of Chemistry, Faculty of Science, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku, Tokyo 162-8601, Japan

3. Tsukuba Research Center for Energy Materials Science (TREMS), Institute of Pure and Applied Sciences, University of Tsukuba 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8573, Japan

Abstract

The regioselectivity for the C–H functionalisation of polycyclic aromatic hydrocarbons is determined not by the C–H cleavage step but by the subsequent reductive elimination step.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT01453G

Reference68 articles.

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2. Development of Preformed Pd Catalysts for Cross-Coupling Reactions, Beyond the 2010 Nobel Prize

3. The Catalytic Cross-Coupling of Unactivated Arenes

4. Oxidative C–H/C–H Coupling Reactions between Two (Hetero)arenes

5. Upgrading Cross-Coupling Reactions for Biaryl Syntheses

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