A copper(i) bromide organic–inorganic zwitterionic coordination compound with a new type of core: structure, luminescence properties, and DFT calculations
Author:
Affiliation:
1. Nikolaev Institute of Inorganic Chemistry
2. Siberian Branch of Russian Academy of Sciences
3. 630090 Novosibirsk
4. Russian Federation
Abstract
A new organic–inorganic Cu(i) bromide complex based on protonated tris(2-pyridyl)phosphine, [(HPy)3PCu2Br5], has been synthesized by a straightforward reaction in solution or by modification of the [Cu2Br2(Py3P)2] complex using hydrobromic acid.
Funder
Russian Foundation for Basic Research
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2020/NJ/D0NJ01835J
Reference34 articles.
1. Photoluminescence Properties of Multinuclear Copper(I) Compounds
2. Binuclear β-diketiminate complexes of copper(i)
3. Hydrogen Bonds Dictate the Coordination Geometry of Copper: Characterization of a Square‐Planar Copper(I) Complex
4. Intramolecular non-covalent interactions as a strategy towards controlled photoluminescence in copper(i) complexes
5. Theoretical studies on how excited state hydrogen and coordination bonds affect luminescent properties of Metal Organic Framework Cu4(L)4•2EtOH
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