A copper(i) bromide organic–inorganic zwitterionic coordination compound with a new type of core: structure, luminescence properties, and DFT calculations

Author:

Berezin Alexey S.1234ORCID,Artem'ev Alexander V.1234ORCID,Komarov Vladislav Y.1234,Baranov Andrey Y.1234

Affiliation:

1. Nikolaev Institute of Inorganic Chemistry

2. Siberian Branch of Russian Academy of Sciences

3. 630090 Novosibirsk

4. Russian Federation

Abstract

A new organic–inorganic Cu(i) bromide complex based on protonated tris(2-pyridyl)phosphine, [(HPy)3PCu2Br5], has been synthesized by a straightforward reaction in solution or by modification of the [Cu2Br2(Py3P)2] complex using hydrobromic acid.

Funder

Russian Foundation for Basic Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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