Cleaner and stronger: how 8-quinolinolate facilitates formation of Co(<scp>iii</scp>)–thiolate from Co(<scp>ii</scp>)–disulfide complexes-Reference-Cited by-同舟云学术

Cleaner and stronger: how 8-quinolinolate facilitates formation of Co(iii)–thiolate from Co(ii)–disulfide complexes

Published:2022 Issue:31 Volume:51 Page:11675-11684
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Marvelous Christian¹^ORCID,de Azevedo Santos Lucas²^ORCID,Siegler Maxime A.³,Fonseca Guerra Célia¹²^ORCID,Bouwman Elisabeth¹^ORCID

Affiliation:

1. Leiden Institute of Chemistry, Gorlaeus Laboratories, Leiden University, P.O. Box 9502, 2300 RA Leiden, The Netherlands

2. Department of Theoretical Chemistry, Amsterdam Institute of Molecular and Life Sciences (AIMMS), Amsterdam Center for Multiscale Modelling (ACMM), Vrije Universiteit Amsterdam, De Boelelaan 1083, 1081 HV Amsterdam, The Netherlands

3. Department of Chemistry, Johns Hopkins University, 3400 N. Charles Street, Baltimore, Maryland 21218, USA

Abstract

The strong ligand-field effect exerted by the exogenous ligand 8-quinolinolate is an important factor contributing to the clean formation of Co(iii)–thiolate complexes from Co(ii)–disulfide compounds in quantitative yields.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT02106D

Reference40 articles.

1. A rational synthesis of coordinated disulfides from coordinated thiols. Crystal structure of [(en)2Co(S(SC2H5)CH2CH2NH2)](ClO4)3.H2O

2. Fine Tuning of the Interaction between the Copper(I) and Disulfide Bond. Formation of a Bis(μ-thiolato)dicopper(II) Complex by Reductive Cleavage of the Disulfide Bond with Copper(I)

3. Interconversion between Bis(μ-thiolato)dicopper(II) and Disulfide-Bridged Dicopper(I) Complexes Mediated by Chloride Ion

4. Oxidative addition of 1,2,5,6-Tetrathiocins to Co(I): A Re-Examination of Crown Ether Functionalized Benzene Dithiolate Cobalt(III) Complexes

5. Metal-mediated thiol–disulfide interconversion—a new tool for metallosupramolecular chemistry

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