Spatially-resolved investigation of the water inhibition of methane oxidation over palladium

Author:

Coney Ciaran1234,Stere Cristina5674ORCID,Millington Paul894,Raj Agnes894,Wilkinson Sam84,Caracotsios Michael10111213,McCullough Geoffrey1424,Hardacre Christopher5674ORCID,Morgan Kevin1234ORCID,Thompsett David894,Goguet Alexandre1234ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering

2. Queen's University Belfast

3. Belfast

4. UK

5. School of Chemical Engineering and Analytical Science

6. University of Manchester

7. Manchester

8. Johnson Matthey Technology Centre

9. Reading RG4 9NH

10. Chemical Engineering Department

11. University of Illinois at Chicago

12. Chicago

13. USA

14. School of Mechanical and Aerospace Engineering

Abstract

Pd/Al2O3 catalysts are known to be active for low temperature methane oxidation reactions, however it has been shown that gases normally associated with methane gas streams (H2O, CO2, H2S) can have an inhibitory effect on the total oxidation reaction.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Reference117 articles.

1. CATALYTIC COMBUSTION OF METHANE OVER PALLADIUM-BASED CATALYSTS

2. IPCC , in 2014: Climate Change 2014: Synthesis Report. Contribution of Working Groups I, II and III to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change , ed. C. W. Team , R. K. Pachauri and L. A. Meyer , IPCC , Geneva, Switzerland , p. 151

3. Active Thermochemical Tables: Sequential Bond Dissociation Enthalpies of Methane, Ethane, and Methanol and the Related Thermochemistry

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