Cyclopentadienylironphosphacarboranes: fragility of polyhedral edges in the 11-vertex system
Author:
Affiliation:
1. Department of Chemistry
2. Faculty of Chemistry and Chemical Engineering
3. Babeş-Bolyai University
4. Cluj-Napoca
5. Romania
6. Department of Chemistry and Center for Computational Quantum Chemistry
7. University of Georgia
8. Athens
9. USA
Abstract
The central FeCPBn−3 polyhedra in all of the lowest energy CpFeCHP(CH3)Bn−3Hn−3. (n = 8 to 12) structures are the most spherical closo deltahedra with adjacent iron and phosphorus atoms and non-adjacent phosphorus and carbon atoms.
Funder
National Science Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/RA/C5RA17070B
Reference26 articles.
1. Chemistry of the polyhedral species derived from transition metals and carboranes
2. Role of metals in borane clusters
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4. The polyborane, carborane, carbocation continuum: architectural patterns
5. The structural significance of the number of skeletal bonding electron-pairs in carboranes, the higher boranes and borane anions, and various transition-metal carbonyl cluster compounds
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1. Isocloso versus closo deltahedra in slightly hypoelectronic supraicosahedral 14-vertex dimetallaboranes with 28 skeletal electrons: relationship to icosahedral dimetallaboranes;New Journal of Chemistry;2020
2. Group 9 metallatelluraboranes: Comparison with their sulfur analogues;Journal of Organometallic Chemistry;2018-06
3. Sulfur and carbon as heteroatoms in ferrathiacarboranes;Polyhedron;2016-07
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