Non-monotonic Soret coefficients of aqueous LiCl solutions with varying concentrations-Reference-Cited by-同舟云学术

Non-monotonic Soret coefficients of aqueous LiCl solutions with varying concentrations

Published:2024 Issue:9 Volume:26 Page:7830-7836
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Lee Namkyu¹²^ORCID,Mohanakumar Shilpa¹^ORCID,Briels W. J.¹³^ORCID,Wiegand Simone¹⁴^ORCID

Affiliation:

1. IBI-4:Biomacromolecular Systems and Processes, Forschungszentrum Jülich GmbH, Jülich D-52428, Germany

2. Department of Mechanical Engineering, Yonsei University, Seoul, Korea

3. University of Twente, Computational Chemical Physics, Postbus 217, Enschede 7500 AE, The Netherlands

4. Chemistry Department – Physical Chemistry, University Cologne, Cologne D-50939, Germany

Abstract

The Soret coefficients’ minimum is due to a minimum in the thermodynamic factor at low concentrations outside the experimental range. This minimum shifts into the experimental range when multiplied by the negative Onsager ratio.

Funder

Yonsei University

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CP/D3CP06061F

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