Aqueous microdroplets containing only ketones or aldehydes undergo Dakin and Baeyer–Villiger reactions
Author:
Affiliation:
1. Department of Chemistry
2. Stanford University
3. Stanford
4. USA
5. State Key Laboratory of Chemical Oncogenomics
6. Shenzhen Deepdrug Information Technology Co. Ltd.
Abstract
The Dakin and Baeyer–Villiger (BV) oxidation reactions require addition of peroxides as oxidants and an acid or a base as a catalyst.
Funder
Air Force Office of Scientific Research
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/SC/C9SC05112K
Reference37 articles.
1. Organic Reactions in Microdroplets: Reaction Acceleration Revealed by Mass Spectrometry
2. Can all bulk-phase reactions be accelerated in microdroplets?
3. Abiotic production of sugar phosphates and uridine ribonucleoside in aqueous microdroplets
4. Selective Synthesis in Microdroplets of 2‐Phenyl‐2,3‐dihydrophthalazine‐1,4‐dione from Phenyl Hydrazine with Phthalic Anhydride or Phthalic Acid
5. Spontaneous formation of gold nanostructures in aqueous microdroplets
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