Solvation/desolvation induced reversible distortion change and switching between spin crossover and single molecular magnet behaviour in a cobalt(<scp>ii</scp>) complex-Reference-Cited by-同舟云学术

Solvation/desolvation induced reversible distortion change and switching between spin crossover and single molecular magnet behaviour in a cobalt(ii) complex

Published:2024 Issue:13 Volume:53 Page:5861-5870
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Zenno Hikaru¹,Sekine Yoshihiro¹²^ORCID,Zhang Zhongyue¹³,Hayami Shinya¹⁴^ORCID

Affiliation:

1. Department of Chemistry, Graduate School of Science and Technology, Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, Japan

2. Priority Organization for Innovation and Excellence, Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, Japan

3. International Research Organization for Advanced Science and Technology, Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, Japan

4. Institute of Industrial Nanomaterials (IINa), Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, Japan

Abstract

The cobalt(ii) compound [Co(MeOphterpy)2](ClO4)2 shows reversible switching between SCO and SMM properties depending on solvation or desolvation.

Funder

Japan Society for the Promotion of Science

Kumamoto University

Sumitomo Foundation

Iketani Science and Technology Foundation

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D3DT03936F

Reference92 articles.

1. Electron transport in molecular junctions

2. Magnetic metal–organic frameworks

3. Magnetic Bistability of Molecules in Homogeneous Solution at Room Temperature

4. A new spin on bistability

5. Molecular spintronics using single-molecule magnets

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